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December 20, 2010
Volume 88, Number 51
p. 20

High-Speed Organic Electro-Optics

Mitch Jacoby

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Ten years ago, the University of Washington's Larry R. Dalton and coworkers turned to materials chemistry to boost the performance of electro-optic devices. The team designed a new type of conjugated organic chromophore and used it to fabricate high-speed electro-optic modulators, replacing standard inorganic crystals, such as lithium niobate, typically used in such devices.

The key property of electro-optic materials that makes them attractive for light-manipulating applications is the ability to change refractive index with an applied electric field. To achieve that effect, the molecules must be aligned in a polymer or other matrix such that there is no center of symmetry.

"Our breakthrough came from understanding how to control the noncovalent interactions that guide lattice formation so that we could build supramolecular assemblies with architectures that are very rare in nature," Dalton says.

Putting that knowledge into practice, Dalton and coworkers designed a chromophore known as CLD-1 that features a bulky segment positioned between its electron-donating and electron-accepting moieties. The goal of that design strategy, which was derived from the team's computational analysis, was to overcome the inherent electrostatic interactions between the molecules that invariably drive them to align centrosymmetrically. It worked like a charm.

The devices Dalton's team made operated on less than 1 V and converted electrical data into optical information at rates exceeding 110 gigahertz. Similarly high data rates had been reported for other polymer-based devices prior to 2000, but those systems required much higher drive voltages, which affected noise levels and limited signal gain. High-speed, low-voltage devices are desired for applications in fiber-optic and satellite communication systems and for optical-switching technology.

The advances reported by Dalton's team a decade ago, which helped meet those application goals, were commercialized by a company called Lumera, based in Bothell, Wash. Lumera was later bought by Gigaoptics, a company with headquarters in Konstanz, Germany, that sells electro-optic devices for terahertz spectroscopy and other laser accessories based on Dalton's original discovery.

Chemical & Engineering News
ISSN 0009-2347
Copyright © 2011 American Chemical Society
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