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January 18, 2010
Volume 88, Number 3
p. 6

New Way To 'Fix' CO2

Electrocatalysis: Process converts CO2 in air into the useful organic feedstock oxalate

Stu Borman

In the presence of CO<sub>2</sub> in air, catalyst (left) reacts to form a complex containing two oxalates (mostly red), which can be liberated by acid treatment. Cu is green, N is blue, S is yellow, O is red, and C is black.
In the presence of CO2 in air, catalyst (left) reacts to form a complex containing two oxalates (mostly red), which can be liberated by acid treatment. Cu is green, N is blue, S is yellow, O is red, and C is black.
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In a study with implications for addressing global warming, researchers have devised a new way to remove the greenhouse gas CO2 from air and form a useful organic feedstock in the process (Science 2010, 327, 313). The technique is still at the demonstration stage but has promising advantages over other CO2 sequestration strategies.

Previously devised processes for “fixing” CO2 include stoichiometric reactions with hydroxide to form carbonate or bicarbonate and catalytic transformations to form organic compounds such as formaldehyde and methanol. Catalytic conversion is more efficient and practical for large-scale use, but current catalysts can’t be used on CO2 in air because they also reduce oxygen, which is present in air at vastly higher levels than CO2. In addition, they are unselective, creating mixtures of organic products.

Inorganic chemist Elisabeth Bouwman of Leiden University, in the Netherlands, and coworkers have now developed a catalyst that reacts with CO2 from ambient air to form a single product: oxalate, a useful feedstock for production of methyl glycolate and other organic compounds. After the reaction, the catalyst is regenerated electrochemically at a very low reduction potential, meaning it is unusually favorable energetically.

The process won’t ameliorate the global warming problem right away—and maybe never will. “Our study is purely fundamental, and the findings will need a lot of additional work before they could possibly be applied in an industrial setting,” Bouwman notes.

Nevertheless, “it’s amazing” that this catalyst reduces CO2 preferentially over oxygen and that the electrochemical step requires so little energy—suggesting that “the catalyst’s structure is almost perfectly matched to the reaction it’s driving,” comments Clifford P. Kubiak of the University of California, San Diego, a specialist in CO2 conversion. Compared with other ways to remove CO2 from air, converting the greenhouse gas to oxalate catalytically, efficiently, and selectively “is near the top of the desirability rankings,” he says.]

Chemical & Engineering News
ISSN 0009-2347
Copyright © 2011 American Chemical Society
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