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December 6, 2010
Volume 88, Number 49
p. 13
Article Appeared Online November 29, 2010
DOI: 10.1021/CEN110910105405

Coal Ash Spill In Tennessee Still A Problem

Environmental Disaster: High levels of arsenic linger downstream of the site of a 2008 accident

Charles Schmidt

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KINGSTON ASH SPILL An aerial image of the Emory River spill site on Dec. 22, 2008, shows coal ash flowing into the river. Tennessee Valley Authority
KINGSTON ASH SPILL An aerial image of the Emory River spill site on Dec. 22, 2008, shows coal ash flowing into the river.

Nearly two years ago, 978,000,000 gallons of wet coal ash spilled into the Emory River and its tributaries near Kingston, Tenn. Now researchers from Duke University report that the spill polluted downstream sediments with unexpectedly high levels of a particularly toxic form of arsenic (Environ. Sci. Technol., DOI: 10.1021/es1026739).

The spill occurred on Dec. 22, 2008, when a holding pond ruptured, releasing its waste from the Tennessee Valley Authority's Kingston Fossil Plant, a coal-fired power plant. Ash produced by burning coal isn't regulated as hazardous waste by the Environmental Protection Agency, because the EPA's testing protocol—known as the Toxicity Characterization Leaching Protocol—assumes that coal ash contaminants do not seep from municipal landfills into nearby water. The TVA spill provided a useful—if tragic—opportunity to test this assumption, says Duke geochemist Avner Vengosh: "It became a huge field experiment."

Soon after the accident, Vengosh and his colleagues descended on the site and launched an investigation that continues today into how the coal ash has affected the river's ecosystems.

For their current report, the team collected over 220 surface water and sediment samples during an 18-month period of TVA's clean up. They measured concentrations of five leachable coal ash contaminants, including arsenic and selenium. The researchers found that anaerobic bacteria in the sediments produce conditions that reduce arsenic from the common pentavalent form to the more-toxic trivalent form, As3+. Meanwhile, selenium leeches out of these anoxic sediments and migrates to the more-oxygenated surface water.

EPA's testing protocol does not predict these findings because it does not consider redox chemistry, explained co-author Helen Hsu-Kim: "The test is only concerned with acid-induced leaching." So it underestimates risks from arsenic under anaerobic disposal conditions, Vengosh says.

The team detected the highest contaminant levels near the spill site in a cove, which received a flowing waste stream during the spill. Given its isolation from the rest of the river, this cove concentrated ash pollutants, whereas in downstream areas with more water exchange, pollutant levels were more diluted. While surface water concentrations of selenium were high only in the cove, As3+ levels were high in sediments throughout the 300-acre spill site and surrounding watershed, Vengosh says.

The Emory River near Kingston, Tenn., after a coal ash spill in 2008. Tennessee Valley Authority
The Emory River near Kingston, Tenn., after a coal ash spill in 2008.

The team also examined the effects of TVA's clean-up methods. Some experts feared that TVA's dredging of nearly two-thirds of the spilled ash would increase surface water contamination. The researchers saw no evidence of such a spike. But even after the remediation, buried ash in some locations still contaminates water among river sediments at arsenic levels beyond 2,000 ppb. In comparison, EPA's maximum contaminant level for arsenic in drinking water is 10 ppb.

EPA is considering whether to designate coal ash as hazardous waste and the Duke team's data are sure to influence that decision, says James Hower, a senior scientist at the University of Kentucky's Center for Applied Energy Research. But designating coal ash as hazardous waste might generate unwanted consequences, he says. For example, it could hamper use of coal ash as filler in concrete production. "There's no doubt these findings are damaging to the coal industry," he says.

Chemical & Engineering News
ISSN 0009-2347
Copyright © 2011 American Chemical Society
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