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August 22, 2011
Volume 89, Number 34
p. 10

Kicking The Coffee-Ring Habit

Fluid Mechanics: Shift in particle shape suppresses vexing effect

Bethany Halford

Spherical particles (1.3 µm across) travel to the edge of an evaporating drop (left), whereas elliptical particles (2 µm long, 0.5 µm wide) are uniformly dispersed. Peter J. Yunker & Arjun Yodh
Spherical particles (1.3 µm across) travel to the edge of an evaporating drop (left), whereas elliptical particles (2 µm long, 0.5 µm wide) are uniformly dispersed.
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A change in particle shape, physicists have discovered, offers a simple way to circumvent the infamous coffee-ring effect (Nature, DOI: 10.1038/nature10344). The phenomenon is characterized by suspended particles accumulating at the edge of a drop of evaporating liquid. It gives coffee stains their distinctive dark edges and complicates the formulation of paints, coatings, and inks.

The problem occurs because most suspended particles are spherical, explains Peter J. Yunker, the graduate student who led the research effort, along with University of Pennsylvania colleagues Tim Still, Matthew A. Lohr, and Arjun G. Yodh. When a drop of liquid evaporates, fluid flows from the center of the droplet outward, taking the suspended spherical particles with it. Yunker and colleagues found that the coffee-ring effect did not occur with elliptical particles.

“Because of their elongated shape, ellipsoids deform the air-water interface,” Yunker explains. “To minimize the total deformation, ellipsoids pack together in clumps on the surface.” These clumps “are difficult to compress or push along the surface, so they prevent ellipsoids from reaching the edge” and result in a uniform deposition of particles.

But paint makers need not shift all their particle shapes from spherical to elliptical. Yunker and colleagues also found that under the right conditions, adding a small amount of elliptical particles to a suspension of spherical ones will also cancel the coffee-ring effect.

The results “may be of great practical importance,” notes Jan Vermant, a chemical engineering professor at Belgium’s Katholieke Universiteit Leuven, in a commentary about the work. He says Yunker’s discovery may also be relevant to things as “mundane as the food we eat or the consumer products we use.” Any item that comes as a cream or emulsion, Vermant says, is subject to the flow of thin films, which resembles the flow when a drop of liquid evaporates and causes the rupture of bubbles in foams or drops in emulsions. Yunker’s work may provide a way to better stabilize such products, he adds.

Peter J. Yunker & Arjun Yodh
Watch microscopic images of particles as they travel in evaporating drops of water.
Chemical & Engineering News
ISSN 0009-2347
Copyright © 2011 American Chemical Society
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