September 17, 2007

Volume 85, Number 38

p. 10

Nuclear Chemistry

Exotic Molecule

Dipositronium molecule contains only electrons and positrons

Elizabeth Wilson

WHEN AN ELECTRON meets its positively charged antimatter counterpart, the positron, they've been known to briefly form an exotic "atom" known as positronium before annihilating each other within nanoseconds in a burst of gamma rays.

Now comes an even more complex matter-antimatter entity: a molecule of two positronium atoms.

David Cassidy

One configuration of a positronium molecule resembles H₂, with central positrons (red) surrounded by electrons (green).

Positronium is somewhat analogous to hydrogen, with the positron playing the role of the proton. It even has a chemical symbol, Ps. Since the 1940s, scientists have speculated about the possibility of creating Ps₂ molecules.

Physicists David B. Cassidy and Allen P. Mills Jr. at the University of California, Riverside, finally orchestrated this marriage of opposites on the internal surface of a thin silica film (Nature 2007, 449, 195).

They collected positrons generated during the beta decay of sodium-22 and shot them onto the film, where the positrons linked up with electrons in the silica pores to form positronium. The energetics of the silica surface then allowed pairs of positronium atoms to bond, albeit briefly. Ps₂ exists for about a quarter of a nanosecond before the electrons and positrons destroy each other.

Haruo Saito, physics professor at the University of Tokyo, remarks that such experiments are difficult, but he believes "that molecular positronium is certainly produced in their experiment."

Cassidy and Mills' work has "profound implications" for one alluring goal: to create a gamma-ray laser, note Northwestern University physicists Arthur J. Freeman and Rolando Saniz. Physicists believe that a dense-enough soup of positronium atoms should form a Bose-Einstein condensate, and an even denser, radiation-stimulated mixture could annihilate itself in an extremely intense, coherent pulse of high-energy photons.

The research invites speculation about even more exotic matter-antimatter combinations, physics professor Clifford M. Surko of the University of California, San Diego, tells C&EN. His group, which developed some of the technology used by Cassidy and Mills, studies, among other things, the binding of positrons to molecules.

"We're beginning to ask questions about the chemistry of antimatter and the chemistry of matter-antimatter interactions," Surko says.

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