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February 5, 2009
Also appeared in print Feb. 9, 2009, p. 10


Atom-sized Quantum Dots

Newly discovered property of silicon atoms may shrink computers

Mitch Jacoby


Click below for a description and an animated depiction of the properties of atomic quantum dots.

Robert A. Wolkow/University of Alberta * Macromedia Flash Player 8 is required to view video.

INDIVIDUAL SILICON ATOMS can exhibit electronic properties typical of quantum dots composed of thousands of atoms, according to researchers at Canada's National Institute for Nanotechnology and the University of Alberta, Edmonton (Phys. Rev. Lett. 2009, 102, 046805). The discovery of atom-sized quantum dots and the associated room-temperature control over individual electrons may lead to a new type of circuitry that drives miniature, low-power computers.

The two electrons in a quantum-dot Si<sub>4</sub> molecule can pinned in place (blue and pink) by judicious position of external charges (green circles). Robert A. Wolkow
The two electrons in a quantum-dot Si4 "molecule" can pinned in place (blue and pink) by judicious positioning of external charges (green circles).

Semiconductor nanocrystals are often called quantum dots because, among other reasons, their electronic energy levels are quantized and discrete—like an atom's. Researchers are studying that property, which ties the color of colloidal nanocrystals to their size for applications such as computing. The idea is to use the electronic states of quantum dots, which are far smaller than today's transistors, to represent the zeros and ones of digital processing.

At present, the working material for that research thrust is some the smallest quantum dots readily available—crystals of about 1,000 atoms. But to use them for computations, researchers must chill the nanocrystals to millikelvin temperatures to prevent them from flipping spontaneously between electronic states. The Edmonton team, led by Robert A. Wolkow, has discovered a way to sidestep those limitations.

Using a scanning tunneling microscope to probe hydrogen-blanketed silicon, the group showed that kicking out a hydrogen atom bonded to silicon results in a negatively charged Si atom that behaves like a quantum dot. Kicking out another nearby hydrogen leads to an artificial Si2 molecule with one electron shuttling between the two atoms (similar to H2+). Then by using a large charge, the team showed that this "bonding" electron can be pins at will, thereby locking the quantum dot into a given electronic state that remains stable even at room temperature.

"These results are remarkable," says Craig S. Lent, professor of electrical engineering at the University of Notre Dame. Wolkow's group has demonstrated a new binary switching mechanism that operates at room temperature and at a truly atomic size scale, he explains. Lent adds "The world is looking for a new binary switch to replace the transistor when size scaling ends. This just might be it."

Click below for a description and an animated depiction of the properties of atomic quantum dots.

Robert A. Wolkow/University of Alberta

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Chemical & Engineering News
ISSN 0009-2347
Copyright © 2009 American Chemical Society


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